- Electronegativity. This increases as you go up the group.
- Atomic Radius, increases as you go down the group.
- Melting point, increases as you go down the group.
- Boiling point, increases as you go down the group.
- The oxidisng agent ability increases and you go up the group (so, Astetine to Fluorine.)
The Sodium Hallides + Sulphuric Acid:
Eqn1 ...
NaCl (solid) + H2SO4 (liquid) => NaHSO4 (solid) + HCl (gas)
This produces steamy fumes of HCl
Eqn2 ...
- NaBr(s) + H2SO4(l) => NaSO4(s) + HBr(g) [Steamy fumes]
-- 2H+ + 2Br- + H2SO4 => SO2 (g) +2H2O(l) + Br(l) [Brown fumes]
Eqn3 ...
- NaI(s) + H2SO4(l) => NaH2SO4(s) + HI(g) [Steamy fumesof HI]
-- 2H+ + 2I- + H2SO4(aq) => H2S(g) + 4H2O(l) + I2(s) [Black solid forms, (I2), bad egg smell.]
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